! Authors: J. Li, Z. Zhao, A. Kazakov, F.L. Dryer, 
! Address: Dept. of Mechanical and Aerospace Engineering, Princeton University, Princeton, NJ 08544
!
! This C1 mechanism is based on the CH3OH mechanism of Held and Dryer (IJCK,1998, 30, 805)
! with following important revision:
! 1.  H2/O2 subset is updated to that of Li et al. (IJCK, in press, 2004)
! 2.  CO + OH = CO2 + H is optimized to fit the literature experimental result 
! 3.  HCO + M = H + CO + M is optimized to fit the literature experimental result
! 4.  CH3 + HO2 = CH3O + OH is modified to match Scire's value at 1000 K 
! 5.  CH3 + HO2 = CH4 + H is taken from Scire (IJCK, 2001, 33, 75)
! 6.  CH3 + O2 = CH2O + OH is taken from Scire (2002, Ph.D. thesis)
! 7.  CH2O + HO2 = HCO + H2O2 is from Eiteneer et al. (JPC A. 1998, 102, 5196)
! 8.  CH2O + H = HCO + H2 is from Irdam et al. (IJCK 1993, 25, 285)
! 9.  CH2O + M reactions are from Friedrichs et al.(IJCK 2004, 36, 157)
! 10. CH3OH decomposition reactions are taken from GRI-3.0 (1999)
! 11. CH2OH + HCO = CH2O + CH2O is taken from Friedrichs et al. (IJCK, 2004, 36, 157)
! 12. CH2OH + HCO = CH3OH + CO is changed to keep the branching ratio with the above reaction
! 13. HCOOH reactions are not included since it is not important and has large uncertainties
! 14. dHf of OH is adjusted to 8.91 kcal/mol (Ruscic et al. JPC A. 2002, 106, 2727)
! 15. thermochemical data of CH2OH is fit to Johnson & Hudgens' table (JPC 1996, 100, 19874)


ELEMENTS
C H O N AR HE
END

SPECIES
CH3OH O2 CO CO2 CH2O H2O CH4 
H2  H2O2  CH3  H  OH  CH2OH
HCO HO2 O CH3O C2H6 AR N2 HE
END

THERMO ALL
0300.00   1000.00 5000.00
HO2               L 5/89H   1O   2   00   00G   200.000  3500.000  1000.000    1
 4.01721090E+00 2.23982013E-03-6.33658150E-07 1.14246370E-10-1.07908535E-14    2
 1.11856713E+02 3.78510215E+00 4.30179801E+00-4.74912051E-03 2.11582891E-05    3
-2.42763894E-08 9.29225124E-12 2.94808040E+02 3.71666245E+00 1.00021620E+04    4
CH2O            NIST/98 C   1H   2O   1    0G   300.000  4000.000 1200.00      1
 0.51481905E+01 0.28678016E-02-0.23782633E-06-0.16111303E-09 0.28566735E-13    2
-0.16230173E+05-0.51213813E+01 0.26962612E+01 0.49261423E-02 0.82826494E-06    3
-0.55038196E-09-0.39610326E-12-0.14970793E+05 0.94697599E+01                   4
AR                120186AR  1               G  0300.00   5000.00  1000.00      1
 0.02500000E+02 0.00000000E+00 0.00000000E+00 0.00000000E+00 0.00000000E+00    2
-0.07453750E+04 0.04366001E+02 0.02500000E+02 0.00000000E+00 0.00000000E+00    3
 0.00000000E+00 0.00000000E+00-0.07453750E+04 0.04366001E+02                   4
CH3O              121686C   1H   3O   1     G  0300.00   3000.00  1000.00      1
 0.03770800E+02 0.07871497E-01-0.02656384E-04 0.03944431E-08-0.02112616E-12    2
 0.01278325E+04 0.02929575E+02 0.02106204E+02 0.07216595E-01 0.05338472E-04    3
-0.07377636E-07 0.02075611E-10 0.09786011E+04 0.01315218E+03                   4
CH3OH             121686C   1H   4O   1     G  0300.00   5000.00  1000.00      1
 0.04029061E+02 0.09376593E-01-0.03050254E-04 0.04358793E-08-0.02224723E-12    2
-0.02615791E+06 0.02378196E+02 0.02660115E+02 0.07341508E-01 0.07170051E-04    3
-0.08793194E-07 0.02390570E-10-0.02535348E+06 0.01123263E+03                   4
CH4               121286C   1H   4          G  0300.00   5000.00  1000.00      1
 0.01683479E+02 0.01023724E+00-0.03875129E-04 0.06785585E-08-0.04503423E-12    2
-0.01008079E+06 0.09623395E+02 0.07787415E+01 0.01747668E+00-0.02783409E-03    3
 0.03049708E-06-0.01223931E-09-0.09825229E+05 0.01372219E+03                   4
CO                121286C   1O   1          G  0300.00   5000.00  1000.00      1
 0.03025078E+02 0.01442689E-01-0.05630828E-05 0.01018581E-08-0.06910952E-13    2
-0.01426835E+06 0.06108218E+02 0.03262452E+02 0.01511941E-01-0.03881755E-04    3
 0.05581944E-07-0.02474951E-10-0.01431054E+06 0.04848897E+02                   4
CO2               121286C   1O   2          G  0300.00   5000.00  1000.00      1
 0.04453623E+02 0.03140169E-01-0.01278411E-04 0.02393997E-08-0.01669033E-12    2
-0.04896696E+06-0.09553959E+01 0.02275725E+02 0.09922072E-01-0.01040911E-03    3
 0.06866687E-07-0.02117280E-10-0.04837314E+06 0.01018849E+03                   4
H                 120186H   1               G  0300.00   5000.00  1000.00      1
 0.02500000E+02 0.00000000E+00 0.00000000E+00 0.00000000E+00 0.00000000E+00    2
 0.02547163E+06-0.04601176E+01 0.02500000E+02 0.00000000E+00 0.00000000E+00    3
 0.00000000E+00 0.00000000E+00 0.02547163E+06-0.04601176E+01                   4
H2                121286H   2               G  0300.00   5000.00  1000.00      1
 0.02991423E+02 0.07000644E-02-0.05633829E-06-0.09231578E-10 0.01582752E-13    2
-0.08350340E+04-0.01355110E+02 0.03298124E+02 0.08249442E-02-0.08143015E-05    3
-0.09475434E-09 0.04134872E-11-0.01012521E+05-0.03294094E+02                   4
H2O                20387H   2O   1          G  0300.00   5000.00  1000.00      1
 0.02672146E+02 0.03056293E-01-0.08730260E-05 0.01200996E-08-0.06391618E-13    2
-0.02989921E+06 0.06862817E+02 0.03386842E+02 0.03474982E-01-0.06354696E-04    3
 0.06968581E-07-0.02506588E-10-0.03020811E+06 0.02590233E+02                   4
H2O2              120186H   2O   2          G  0300.00   5000.00  1000.00      1
 0.04573167E+02 0.04336136E-01-0.01474689E-04 0.02348904E-08-0.01431654E-12    2
-0.01800696E+06 0.05011370E+01 0.03388754E+02 0.06569226E-01-0.01485013E-05    3
-0.04625806E-07 0.02471515E-10-0.01766315E+06 0.06785363E+02                   4
HCO               121286H   1C   1O   1     G  0300.00   5000.00  1000.00      1
 0.03557271E+02 0.03345573E-01-0.01335006E-04 0.02470573E-08-0.01713851E-12    2
 0.03916324E+05 0.05552299E+02 0.02898330E+02 0.06199147E-01-0.09623084E-04    3
 0.01089825E-06-0.04574885E-10 0.04159922E+05 0.08983614E+02                   4
O                 120186O   1               G  0300.00   5000.00  1000.00      1
 0.02542060E+02-0.02755062E-03-0.03102803E-07 0.04551067E-10-0.04368052E-14    2
 0.02923080E+06 0.04920308E+02 0.02946429E+02-0.01638166E-01 0.02421032E-04    3
-0.01602843E-07 0.03890696E-11 0.02914764E+06 0.02963995E+02                   4
O2                121386O   2               G  0300.00   5000.00  1000.00      1
 0.03697578E+02 0.06135197E-02-0.01258842E-05 0.01775281E-09-0.01136435E-13    2
-0.01233930E+05 0.03189166E+02 0.03212936E+02 0.01127486E-01-0.05756150E-05    3
 0.01313877E-07-0.08768554E-11-0.01005249E+05 0.06034738E+02                   4
N2                121286N   2               G  0300.00   5000.00  1000.00      1
 0.02926640E+02 0.01487977E-01-0.05684761E-05 0.01009704E-08-0.06753351E-13    2
-0.09227977E+04 0.05980528E+02 0.03298677E+02 0.01408240E-01-0.03963222E-04    3
 0.05641515E-07-0.02444855E-10-0.01020900E+05 0.03950372E+02                   4
CH3               IU0702C  1.H  3.   0.   0.G   200.000  6000.000 1000.        1
 0.29781206E+01 0.57978520E-02-0.19755800E-05 0.30729790E-09-0.17917416E-13    2
 0.16509513E+05 0.47224799E+01 0.36571797E+01 0.21265979E-02 0.54583883E-05    3
-0.66181003E-08 0.24657074E-11 0.16422716E+05 0.16735354E+01 0.17643935E+05    4
CH2OH              JH/96C   1H   3O   1N   0G   250.000  3000.000  750.00      1
 0.37469103E+01 0.88646121E-02-0.42580722E-05 0.10088040E-08-0.94501561E-13    2
-0.36664824E+04 0.54281095E+01 0.46119792E+01-0.31203760E-02 0.35531680E-04    3
-0.49379398E-07 0.22027247E-10-0.36040734E+04 0.28351399E+01                   4
C2H6              121686C   2H   6          G  0300.00   4000.00  1000.00      1
 0.04825938E+02 0.01384043E+00-0.04557259E-04 0.06724967E-08-0.03598161E-12    2
-0.01271779E+06-0.05239507E+02 0.01462539E+02 0.01549467E+00 0.05780507E-04    3
-0.01257832E-06 0.04586267E-10-0.01123918E+06 0.01443229E+03                   4
OH                S 9/01O   1H   1    0    0G   200.000  6000.000 1000.        1
 2.86472886E+00 1.05650448E-03-2.59082758E-07 3.05218674E-11-1.33195876E-15    2
 3.68362875E+03 5.70164073E+00 4.12530561E+00-3.22544939E-03 6.52764691E-06    3
-5.79853643E-09 2.06237379E-12 3.34630913E+03-6.90432960E-01 4.51532273E+03    4
HE                120186HE  1               G  0300.00   5000.00  1000.00      1
 0.02500000E+02 0.00000000E+00 0.00000000E+00 0.00000000E+00 0.00000000E+00    2
-0.07453750E+04 0.09153489E+01 0.02500000E+02 0.00000000E+00 0.00000000E+00    3
 0.00000000E+00 0.00000000E+00-0.07453750E+04 0.09153488E+01                   4
END

REACTIONS

! ************ H2-O2 Chain Reactions **********************

! Hessler, J. Phys. Chem. A, 102:4517 (1998)
H+O2=O+OH                 3.547e+15 -0.406  1.6599E+4

! Sutherland et al., 21st Symposium, p. 929 (1986)
O+H2=H+OH                 0.508E+05  2.67  0.629E+04

! Michael and Sutherland, J. Phys. Chem. 92:3853 (1988)
H2+OH=H2O+H               0.216E+09  1.51  0.343E+04

! Sutherland et al., 23rd Symposium, p. 51 (1990)
O+H2O=OH+OH               2.97e+06   2.02  1.34e+4

! *************** H2-O2 Dissociation Reactions ******************

! Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986)
H2+M=H+H+M                4.577E+19 -1.40  1.0438E+05
   H2/2.5/ H2O/12/
   CO/1.9/ CO2/3.8/
   AR/0.0/ HE/0.0/

! Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986)
H2+AR=H+H+AR              5.84e18   -1.1   1.0438E+05
H2+HE=H+H+HE              5.84e18   -1.1   1.0438E+05

! Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986)
O+O+M=O2+M                6.165E+15 -0.50  0.000E+00
   H2/2.5/ H2O/12/
   AR/0.0/  HE/0.0/
   CO/1.9/ CO2/3.8/

! Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986)
O+O+AR=O2+AR              1.886E+13 0.00  -1.788E+03

O+O+HE=O2+HE              1.886E+13 0.00  -1.788E+03

! Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986)
O+H+M=OH+M                4.714E+18 -1.00  0.000E+00
   H2/2.5/ H2O/12/
   AR/0.75/ HE/0.75/
   CO/1.9/ CO2/3.8/

! Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986)
!H+OH+M=H2O+M              2.212E+22 -2.00  0.000E+00
H+OH+M=H2O+M               3.800E+22 -2.00  0.000E+00
   H2/2.5/ H2O/12/
   AR/0.38/ HE/0.38/
   CO/1.9/ CO2/3.8/

!************** Formation and Consumption of HO2******************

! Cobos et al., J. Phys. Chem. 89:342 (1985) for kinf
! Michael, et al., J. Phys. Chem. A, 106:5297 (2002) for k0

!******************************************************************************
! MAIN BATH GAS IS N2 (comment this reaction otherwise)
!
 H+O2(+M)=HO2(+M)      1.475E+12  0.60  0.00E+00
     LOW/6.366E+20  -1.72  5.248E+02/
     TROE/0.8  1E-30  1E+30/
     H2/2.0/ H2O/11./ O2/0.78/ CO/1.9/ CO2/3.8/

!******************************************************************************
! MAIN BATH GAS IS AR OR HE (comment this reaction otherwise)
!
!H+O2(+M)=HO2(+M)      1.475E+12  0.60  0.00E+00
!    LOW/9.042E+19  -1.50  4.922E+02/
!    TROE/0.5 1E-30  1E+30/
!    H2/3.0/ H2O/16/ O2/1.1/ CO/2.7/ CO2/5.4/ HE/1.2/

! Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986) [modified]
HO2+H=H2+O2               1.66E+13   0.00   0.823E+03

! Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986) [modified]
HO2+H=OH+OH               7.079E+13   0.00   2.95E+02

! Baulch et al., J. Phys. Chem. Ref Data, 21:411 (1992)
HO2+O=O2+OH               0.325E+14  0.00   0.00E+00

! Keyser, J. Phys. Chem. 92:1193 (1988)
HO2+OH=H2O+O2             2.890E+13  0.00 -4.970E+02

! ***************Formation and Consumption of H2O2******************

! Hippler et al., J. Chem. Phys. 93:1755 (1990)
HO2+HO2=H2O2+O2            4.200e+14  0.00  1.1982e+04
  DUPLICATE
HO2+HO2=H2O2+O2            1.300e+11  0.00 -1.6293e+3
  DUPLICATE

! Brouwer et al., J. Chem. Phys. 86:6171 (1987) for kinf
! Warnatz, J. in Combustion chemistry (1984) for k0
H2O2(+M)=OH+OH(+M)         2.951e+14   0.00  4.843E+04
  LOW/1.202E+17  0.00  4.55E+04/
  TROE/0.5 1E-30 1E+30/
  H2/2.5/ H2O/12/
  CO/1.9/ CO2/3.8/
  AR/0.64/ HE/0.64/

! Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986)
H2O2+H=H2O+OH             0.241E+14  0.00  0.397E+04

! Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986)
H2O2+H=HO2+H2             0.482E+14  0.00  0.795E+04

! Tsang and Hampson, J. Phys. Chem. Ref. Data, 15:1087 (1986)
H2O2+O=OH+HO2             9.550E+06  2.00  3.970E+03

! Hippler and Troe, J. Chem. Phys. Lett. 192:333 (1992)
H2O2+OH=HO2+H2O           1.000E+12  0.00  0.000
    DUPLICATE
H2O2+OH=HO2+H2O           5.800E+14  0.00  9.557E+03
    DUPLICATE

!************** CO/HCO REACTIONS *****************

! Troe, 15th Symposium
CO+O(+M)=CO2(+M)           1.80E+10  0.00  2384.
! Fit of Westmoreland, AiChe J., 1986, rel. to N2 - Tim adjusted from MTA's
! rate constant, which was rel to Ar.
   LOW/1.55E+24 -2.79  4191./
   H2/2.5/ H2O/12/ AR/0.87/ CO/1.9/ CO2/3.8/

! Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
CO+O2=CO2+O               0.253E+13  0.00  0.477E+05

! This rate constant is modified per an updated value for HO2+HO2=H2O2+OH
CO+HO2=CO2+OH             3.01E+13   0.00   2.30E+04

! This study (2004) by matching literature experiment results
CO+OH=CO2+H                    2.229E+05  1.89  -1158.7

! This study (2004) by matching literature experiment results
HCO+M=H+CO+M           4.7485E+11  0.659  1.4874E+04
H2/2.5/ H2O/6/ CO/1.9/ CO2/3.8/

! Timonen et al., JPC, 92:651 (1988)
HCO+O2=CO+HO2             0.758E+13  0.00  0.410E+03 

! Timonen et al., JPC, 91:692 (1987)
HCO+H=CO+H2               0.723E+14  0.00  0.000E+00  

! Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
HCO+O=CO+OH               0.302E+14  0.00  0.000E+00  

! Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
HCO+OH=CO+H2O             0.302E+14  0.00  0.000E+00

! All reactions from Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
HCO + O = CO2 + H                 3.000E+13  0.00  0.000E+00
HCO + HO2 = CO2 + OH + H          3.000E+13  0.00  0.000E+00
HCO + CH3 = CO + CH4              1.200E+14  0.00  0.000E+00
HCO + HCO = H2 + CO + CO          3.000E+12  0.00  0.000E+00

! Glarborg et al., Combust Flame, 132:629 (2003)
HCO + HCO = CH2O + CO            3.0E+13  0.00  0.00

!**************************  ch2o Reactions   ************************

! Friedrichs et al., IJCK, 36:157 (2004)
 CH2O + M = HCO + H + M             3.3E+39  -6.3  9.99E+04
 H2/2.5/ H2O/12.0/ CO/1.9/ CO2/3.8/ AR/0.7/

 CH2O + M = CO + H2 + M             3.1E+45  -8.0  9.751E+04
 H2/2.5/ H2O/12.0/ CO/1.9/ CO2/3.8/ AR/0.7/

! Irdam et al., IJCK, 25:285 (1993)
CH2O + H = HCO + H2                5.74E+07  1.9  2.7486E+03

! Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
CH2O + O = HCO + OH               1.810E+13  0.00  3.080E+03

!Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
CH2O + OH = HCO + H2O             3.430E+09  1.18 -4.470E+02

!Hidaka et al. Combust Flame 92:365 (1993)
CH2O + O2 = HCO + HO2             1.23e+6 3.00 52000.

!Eiteneer et al, JPC A. 102:5196 (1998)
  CH2O + HO2 = HCO + H2O2           4.11E+4   2.5  10210.

!Fischer et al. IJCK, 32:713 (2000)
CH2O+CH3 = HCO+CH4  3.636E-06   5.42  9.980E+02

!**************************  ch4 Reactions******************************

! Slagle et al., JPC, 91:4375 (1987)
CH3 + O = CH2O + H                8.430E+13  0.00  0.000E+00

! Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
CH3 + O2 = CH3O + O               1.990E+18 -1.57  2.923E+04

!Scire et al. IJCK, 33:75 (2001)
CH3 + O2 = CH2O + OH              3.74e+11 0.0 14640.

! Jim Scire (Ph.D. thesis, 2002)only for 1000 K
! CH3 + HO2 = CH3O + OH              1.48e+13   0.00  0.00

!Zhu and Lin (2001, J.Phys.Chem.A 105)
!CH3 + HO2 = CH3O + OH              6.14244e+10  0.76 -2325  !1000-3000k
!CH3 + HO2 = CH3O + OH              1.78853e+14 -0.24 -361.67 !300-1000k

! This study (2004) by modifing Zhu & Lin's to match Jim's value at 1000K
 CH3 + HO2 = CH3O + OH              2.41e+10   0.76 -2325

! Walter et al. 23rd Symp. (Int.) Combust. p107 (1990)
CH3+CH3(+M) = C2H6(+M) 9.214E+16  -1.17  6.358E+02
 LOW/1.135E+36 -5.246  1.705E+03/
 TROE/0.405 1120. 69.6 1.E+15/
  H2/2/ H2O/5/ CO/2/ CO2/3/

!GRI mech 1.2
 CH3+H(+M) = CH4(+M)            1.270E+16   -0.630    383.00 
      LOW  /  2.477E+33   -4.760   2440.00/
      TROE/  0.7830   74.00  2941.00  6964.00 /
    H2/2.0/ H2O/6.0/ CH4/2.0/ CO/1.5/ CO2/2.0/ C2H6/3.0/ AR/0.7/

! Schatz et al., JPC, 88:221 (1984)
CH4 + H = CH3 + H2                5.470E+07  1.97  1.121E+04

! Klemm et al. 18th Symp. (Int) Combust. p785 (1981)
CH4 + O = CH3 + OH                3.150E+12  0.50  10290.0

! Felder and Madronich, CST, 50:135 (1986)
CH4 + OH = CH3 + H2O              5.720E+06  1.96  2.639E+03

! Scire et al. IJCK, 33:75 (2001)
CH3 + HO2 = CH4 + O2               3.16E+12   0.00  0.00

! Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
CH4 + HO2 = CH3 + H2O2            1.810E+11  0.00  1.858E+04

!**************************  ch3oh/ch2oh Reactions **********************

! Cribb et al. Combust Flame, 88:186 (1992)
 CH2OH + M = CH2O + H + M    1.0E+14 0.0 25.1E+3

! Tsang, JPC Ref. Data, 16:471 (1987)
CH2OH + H = CH2O + H2             6.000E+12  0.00  0.000E+00

! Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
CH2OH + H = CH3 + OH              9.635E+13  0.00  0.000E+00

! Tsang, JPC Ref. Data, 16:471 (1987)
CH2OH + O = CH2O + OH             4.200E+13  0.00  0.000E+00

! Tsang, JPC Ref. Data, 16:471 (1987)
CH2OH + OH = CH2O + H2O           2.400E+13  0.00  0.000E+00

! Grotheer et al., JPC, 92:4028 (1988)
! used in Norton and Dryer, IJCK, 22:219 (1990)
! However, they only used the high temperature portion of the fit. The high
! temperature portion alone is 75% of the total at 700K, 92.8% at 1000 K
 CH2OH + O2 = CH2O + HO2           2.410E+14  0.00  5.017E+03
    DUP
 CH2OH + O2 = CH2O + HO2           1.510E+15 -1.00  0.000E+00
   DUP

! Tsang, JPC Ref. Data, 16:471 (1987)
CH2OH + HO2 = CH2O + H2O2         1.200E+13  0.00  0.000E+00

! This study (2004) by keeping the branching ratio if using Friedrichs et al. (2004) below
CH2OH + HCO = CH3OH + CO          1.000E+13  0.00  0.000E+0

! Friedrichs et al. (IJCK, 2004, 36, 157)
CH2OH + HCO = CH2O + CH2O         1.500E+13  0.00  0.000E+00

!******* Ethylene glycol formation ****************

! Tsang, JPC Ref. Data, 16:471 (1987)
 2CH2OH = CH3OH + CH2O             3.000E+12  0.00  0.000E+00

! Tsang, JPC Ref. Data, 16:471 (1987)
 CH2OH + CH3O = CH3OH + CH2O       2.400E+13  0.00  0.000E+00

!********* CH3O reactions *************

! Page et al., JPC, 93:4404 (1989)
CH3O + M = CH2O + H + M           8.300E+17 -1.20  1.550E+04 !MC Lin

! Wantuck et al., JPC, 91:4653 (1987)
CH3O + H = CH3 + OH               3.200E+13  0.00  0.000E+00

! Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
CH3O + O = CH2O + OH              6.000E+12  0.00  0.000E+00

! Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
CH3O + OH = CH2O + H2O            1.800E+13  0.00  0.000E+00

! Wantuck et al., JPC, 91:4653 (1987)
CH3O + O2 = CH2O + HO2              9.033E+13  0.00  1.198E+04
  DUP
CH3O + O2 = CH2O + HO2              2.200E+10  0.00  1.748E+03
  DUP

! Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
CH3O + HO2 = CH2O + H2O2          3.000E+11  0.00  0.000E+00

! Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
CH3O + CO = CH3 + CO2             1.600E+13  0.00  1.180E+04

! Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
CH3O + HCO = CH3OH + CO           9.000E+13  0.00  0.000E+00

! Tsang and Hampson, JPC Ref. Data, 15:1087 (1986)
2CH3O = CH3OH + CH2O              6.000E+13  0.00  0.000E+00

!********* CH3OH reactions ***********

! GRI-3.0 (1999)
OH+CH3(+M)<=>CH3OH(+M)                   2.790E+18   -1.430    1330.00
     LOW  /  4.000E+36   -5.920   3140.00/
     TROE/   .4120  195.0  5900.00  6394.00/
H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/

H+CH2OH(+M)<=>CH3OH(+M)                  1.055E+12     .500      86.00
     LOW  /  4.360E+31   -4.650   5080.00/
     TROE/   .600  100.00  90000.0  10000.0 /
H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/

H+CH3O(+M)<=>CH3OH(+M)                   2.430E+12     .515      50.00
     LOW  /  4.660E+41   -7.440   14080.0/
     TROE/   .700  100.00  90000.0 10000.00 /
H2/2.00/ H2O/6.00/ CH4/2.00/ CO/1.50/ CO2/2.00/ C2H6/3.00/

! Warnatz, in Gardiner, Jr. Combustion chemistry (1984)
 CH3OH + H = CH2OH + H2            3.200E+13  0.00  6.095E+03
 CH3OH + H = CH3O + H2             8.000E+12  0.00  6.095E+03 

! Tsang, JPC Ref. Data, 16:471 (1987)
CH3OH + O = CH2OH + OH            3.880E+05  2.50  3.080E+03

! Bott and Cohen, IJCK, 23:1075 (1991) {356}
CH3OH + OH = CH3O + H2O           1.000E+06  2.10  4.967E+02
CH3OH + OH = CH2OH + H2O          7.100E+06  1.80 -5.960E+02

! Tsang, JPC Ref. Data, 16:471 (1987)
CH3OH + O2 = CH2OH + HO2          2.050E+13  0.00  4.490E+04

! Tsang, JPC Ref. Data, 16:471 (1987)
CH3OH + HCO = CH2OH + CH2O        9.635E+03  2.90  1.311E+04

! Cathonnet et al., J. Chim. Phys., 79:475 (1982)
 CH3OH + HO2 = CH2OH + H2O2        3.980E+13  0.00  1.940E+04

! Tsang, JPC Ref. Data, 16:471 (1987)
CH3OH + CH3 = CH2OH + CH4         3.190E+01  3.17  7.172E+03

! Tsang, JPC Ref. Data, 16:471 (1987)
CH3O + CH3OH = CH3OH + CH2OH      3.000E+11  0.00  4.060E+03


END
